Course Overview

前半では,ウエルナー型金属錯体の電子構造(配位子場分裂、スペクトル項など),金属錯体の反応(配位子交換反応及びその反応機構,酸化還元反応(電子移動のマーカス理論の初歩を含む),光化学反応)を扱う。後半では,有機金属錯体に関して,18電子則,π逆供与,分子軌道に基づく構造と性質の理解を促し,酸化的付加及び還元的脱離を含む基本的な反応形態について述べた後,代表的な触媒反応及びその機構について言及する。

Learning Achievement

Competence

Knowledge and understanding in the field of inorganic and analytical chemistry and those application to related fields

Course prerequisites

Learning "Inorganic chemistry I" in the second year should be required.

Grading Philosophy

Two examinations will be made to evaluate the achievements at the end of each half (after 15th lecture).

Course schedule

Crystal field theory (1)
Crystal field theory (2)
Crystal field theory (3)
Crystal field theory (4)
Ligand field theory (1)
Absorption spectra of transition metal complexes 1
Absorption spectra of transition metal complexes 2
Reactions of metal complexes (1)
Reactions of metal complexes (2)
Ligand substitution reactions of square-planar complexes
Ligand substitution reactions of octahedral complexes 1
Ligand substitution reactions of octahedral complexes 2
Redox reactions of metal complexes 1
Redox reactions of metal complexes 2
Photochemical reactions of metal complexes
Basic background of organometallic chemistry
organometallic chemistry 1
organometallic chemistry 2
organometallic chemistry 3
organometallic chemistry 4
organometallic chemistry 5
organometallic chemistry 6
organometallic chemistry 7
Reactions of organometallic complexes
Catalysis of organometallic complexes 1
Catalysis of organometallic complexes 2
Catalysis of organometallic complexes 3
Catalysis of organometallic complexes 4
Catalysis of organometallic complexes 5
Catalysis of organometallic complexes 6

Course type

Lectures

Online Course Requirement

Instructor

Kojima Takahiko

Other information

Site for Inquiry

Link to the syllabus provided by the university